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pi-Stacking and hydrogen bonding direct diastereoselectivity in one-pot syntheses of octahedral iron(II) complexes

Constable, E. C. and Zhang, G. and Housecroft, C. E. and Neuburger, M. and Zampese, J. A.. (2010) pi-Stacking and hydrogen bonding direct diastereoselectivity in one-pot syntheses of octahedral iron(II) complexes. Chemical Communications, 46 (18). pp. 3077-3079.

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Official URL: http://edoc.unibas.ch/dok/A5841495

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Abstract

One-pot reactions of FeCl(2).4H(2)O and 2,2'-bipyridine-6-carbaldehyde with enantiopure chiral amines lead to octahedral [FeL(2)](2+) complexes, the diastereoselectivity of which depends on the nature of the amine; an interplay of intra-cation pi-stacking and hydrogen bonding directs the diastereoselectivity.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Housecroft, Catherine Elizabeth and Constable, Edwin Charles and Zhang, Guoqi and Zampese, Jennifer Ann and Neuburger, Markus
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
ISSN:0022-4936
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:01 Dec 2016 07:41
Deposited On:14 Sep 2012 06:59

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