Constable, E. C. and Zhang, G. and Housecroft, C. E. and Neuburger, M. and Zampese, J. A.. (2010) pi-Stacking and hydrogen bonding direct diastereoselectivity in one-pot syntheses of octahedral iron(II) complexes. Chemical Communications, 46 (18). pp. 3077-3079.
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Official URL: http://edoc.unibas.ch/dok/A5841495
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Abstract
One-pot reactions of FeCl(2).4H(2)O and 2,2'-bipyridine-6-carbaldehyde with enantiopure chiral amines lead to octahedral [FeL(2)](2+) complexes, the diastereoselectivity of which depends on the nature of the amine; an interplay of intra-cation pi-stacking and hydrogen bonding directs the diastereoselectivity.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Housecroft) |
|---|---|
| UniBasel Contributors: | Housecroft, Catherine Elizabeth and Constable, Edwin Charles and Zhang, Guoqi and Zampese, Jennifer Ann and Neuburger, Markus |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 0022-4936 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 01 Dec 2016 07:41 |
| Deposited On: | 14 Sep 2012 06:59 |
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