Constable, Edwin C. and Zhang, Guoqi and Housecroft, Catherine E. and Neuburger, Markus. (2010) A hexadentate Schiff base ligand which undergoes reversible, diastereoselective addition of methanol. Journal of Molecular Structure , 975 (1-3). pp. 367-371.
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Official URL: http://edoc.unibas.ch/dok/A5841496
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Abstract
Condensation of enantiopure (S)-(−)- or (R)-(+)-1,1′-binaphthyl-2,2′-diamine with 2,2′-bipyridine-6-carbaldehyde in dry toluene gives enantiopure (S)-2 and (R)-2, but in MeOH/CH2Cl2, diastereoselective addition of MeOH occurs across the imine bonds of (S)-2 to give (S,S,S)-3; in CH2Cl2, CHCl3 or CH3CN, (S,S,S)-3 eliminates MeOH, reverting to (S)-2.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Housecroft) |
|---|---|
| UniBasel Contributors: | Housecroft, Catherine Elizabeth and Constable, Edwin Charles and Zhang, Guoqi and Neuburger, Markus |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Elsevier |
| ISSN: | 0022-2860 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: | |
| Last Modified: | 08 May 2017 07:51 |
| Deposited On: | 14 Sep 2012 06:59 |
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