Capturing copper(II) ions using {Cu(tpy)(bpy)} domains

Constable, Edwin C. and Housecroft, Catherine E. and Price, Jason R. and Zampese, Jennifer A.. (2010) Capturing copper(II) ions using {Cu(tpy)(bpy)} domains. Inorganic Chemistry Communications, 13 (5). pp. 683-685.

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Official URL: http://edoc.unibas.ch/dok/A5841497

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The reaction of 6,6"'-dimethyl-2,2':6',2":6",2'"-quaterpyridine (2) with 2,2':6',2"-terpyridine (tpy) and Cu(NO3)·3H2O leads to the formation of [Cu(tpy)(2)]2+ and [Cu2(tpy)2(2)]4+, isolated as the hexafluoridophosphate salts. Single crystal structures of [Cu2(tpy)2(2)][PF6]4·2H2O and [Cu(tpy)(2)][PF6]2·MeCN are presented and illustrate the special stability of the 5-coordinate {Cu(tpy)(bpy)}2+ motif in mono- and dinuclear environments.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Housecroft)
UniBasel Contributors:Housecroft, Catherine Elizabeth and Constable, Edwin Charles and Price, Jason Roy and Zampese, Jennifer Ann
Item Type:Article, refereed
Article Subtype:Research Article
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:08 May 2017 07:23
Deposited On:14 Sep 2012 06:53

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