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4′-Chloro-2,2′:6′,2″-terpyridine (L): ethyl sulfate salts of [H2L]2+ and the single crystal structures of [H2L][EtOSO3]Cl · H2O and [ML2][PF6]2 with M = Fe and Ru

Beves, Jonathon E. and Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia and Zampese, Jennifer A.. (2008) 4′-Chloro-2,2′:6′,2″-terpyridine (L): ethyl sulfate salts of [H2L]2+ and the single crystal structures of [H2L][EtOSO3]Cl · H2O and [ML2][PF6]2 with M = Fe and Ru. Inorganic Chemistry Communications, 11 (9). pp. 1006-1008.

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Official URL: http://edoc.unibas.ch/dok/A5248850

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Abstract

The preparation and characterization of [H(2)1][ErOSO3](2) and the crystal structure of [H(2)1][EtOSO3]Cl center dot H2O are reported (1 =4`-chloro-2,2`:6`,2 ``-terpyridine): extensive hydrogen bonding dictates both the conformation of the tpy domain and the crystal packing. An efficient microwave oven synthesis of [Ru(1)(2)][PF6](2) is described; the method has general application for [Ru(tpy)(2)](2+) derivatives. In the solid state, [Ru(1)(2)][PF6](2) and [Fe(1)(2)[[PF6](2) are isostructural and crystallize in the tetragonal P42(1)c space group.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:1387-7003
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 06:39
Deposited On:22 Mar 2012 14:18

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