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The Systematic Synthesis of Heterobimetallic Double-helical Complexes of 2,2' : 6' ,2'' : 6'' ,2''' : 6''',2'''' -Quinquepyridines

Constable, E. C. and Walker, J. V.. (1992) The Systematic Synthesis of Heterobimetallic Double-helical Complexes of 2,2' : 6' ,2'' : 6'' ,2''' : 6''',2'''' -Quinquepyridines. Chemical Communications, 28 (12). pp. 884-886.

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Official URL: http://edoc.unibas.ch/dok/A5248885

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Abstract

2,2':6',2'':6'',2''':6''',2''''-Quinquepyridine ligands (L) form double-helical 2:2 or mono-helical 1:1 complexes with transition metals; solutions of cobalt(II) complexes contain the monohelical seven-coordinate cation [CoL(S)2]2+ (S = H2O, MeOH or MeCN) which reacts with silver(I) or copper(I) to give the heterobinuclear double-helical complexes [CoML2]3+.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
Item Type:Article, refereed
Bibsysno:Link to catalogue
Publisher:Royal Society of Chemistry
ISSN:0022-4936
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:01 Dec 2016 07:58
Deposited On:22 Mar 2012 14:08

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