Constable, E. C. and Elder, S. M. and Raithby, P. R. and Ward, M. D.. (1991) The preparation and structural characterization of a double-helical binuclear dicobalt(II) complex of 2,2′: 6′,2″: 6″,2‴: 6‴, 2‴-quinquepyridine; the x-ray crystal structure of acetato(O,O′)bis (2,2′: 6′,2″: 6″,2‴: 6‴, 2‴-quinquepyridine)dicobalt(II) hexafluorophosphate tris-acetonitrile solvate. Polyhedron, 10 (12). pp. 1395-1400.
Full text not available from this repository.
Official URL: http://edoc.unibas.ch/dok/A5248889
Downloads: Statistics Overview
Abstract
The reaction of cobalt(II) acetate with 2,2`:6`,2``:6``,2```:6```,2````-quinquepyridine (L) in acetonitrile results in the spontaneous assembly of a binuclear double helical complex. The electrochemical behaviour of this compound is complex. The driving force for the assembly of the complex is probably associated with the close stacking contacts between approximately co-planar pyridine rings; there are no direct metal-metal interactions.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable) |
|---|---|
| Item Type: | Article, refereed |
| Publisher: | Pergamon Press |
| ISSN: | 0277-5387 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
|
| Last Modified: | 26 Aug 2019 15:48 |
| Deposited On: | 22 Mar 2012 14:07 |
Repository Staff Only: item control page