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Diastereoselective complex formation with a simple C-2-symmetric hexadentate ligand based on a 1,1 '-binaphthalene scaffold

Constable, Edwin C. and Zhang, Guoqi and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia. (2009) Diastereoselective complex formation with a simple C-2-symmetric hexadentate ligand based on a 1,1 '-binaphthalene scaffold. Dalton Transactions, 7 (39). pp. 8165-8167.

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Official URL: http://edoc.unibas.ch/dok/A5251517

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Abstract

A pair of enantiomerically pure ligands have been prepared from the condensation of (S)-(-)-1,1'-binaphthalene-2,2'-diamine or (R)-(+)-1,1'-binaphthalene-2,2'-diamine with two equivalents of 2,2'-bipyridine-6-carbaldehyde. The reaction of these new hexadentate ligands with iron(II) salts results in diastereomerically pure complexes in which the stereochemistry at the metal is fully defined by the chiral ligand scaffold. The simplicity of synthesis of the ligand suggests that conjugates of this type could play an important role in inorganic stereoselective synthesis.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
ISSN:1477-9226
e-ISSN:1477-9234
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:08 May 2017 08:39
Deposited On:22 Mar 2012 14:06

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