Cornioley-Deuschel, Christine and Ward, Thomas R. and Von Zelewsky, Alex. (1988) Complexes with pincers : 2,6-Diphenylpyridine as twofold-deprotonated terdentate ligand in C,C-trans-, and as mono-deprotonated chelate ligand in chiral C,C-cis-complexes of platinum(II) and palladium(II). Helvetica Chimica Acta, 71 (1). pp. 130-133.
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Official URL: http://edoc.unibas.ch/dok/A5254440
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Abstract
A2,6-Diphenylpyridine forms, as twofold-deprotonated, terdentate ligand, complexes with Pt(II) and Pd(II), having two adjacent five-membered metallocycles. As mono-deprotonated, bidentate ligand, it forms cis-bis-complexes having a chirality axis. Pt(II) complexes undergo thermal and photochemical oxidative addition reactions, yielding stable Pt(IV) compounds. Pd(II) complexes yield substitued 2,6-diphenylpyridine in photochemical reactions.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward) |
|---|---|
| UniBasel Contributors: | Ward, Thomas R. R. |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 0018-019X |
| e-ISSN: | 1522-2675 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: | |
| Last Modified: | 03 May 2017 08:20 |
| Deposited On: | 22 Mar 2012 14:06 |
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