Ward, Thomas R. and Collot, Jerome and Gradinaru, Julieta and Loosli, Andreas and Skander, Myriem and Letondor, Christophe and Joseph, Edith and Klein, Gerard. (2003) Exploiting the second coordination sphere : proteins as host for enantioselective catalysis. Chimia, 57 (10). pp. 586-588.
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Abstract
With the aim of exploring the role of the second coordination sphere in enantioselective catalysis, achiral organometallic catalyst precursors are anchored in proteins via non-covalent interactions. A chemogenetic procedure allows the activity and the enantioselectivity of the artificial metalloenzymes to be optimized, to yield hybrid catalysts with features reminiscent both of enzymatic and homogeneous catalysts.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward) |
|---|---|
| UniBasel Contributors: | Ward, Thomas R. R. |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Schweizerische Chemische Gesellschaft |
| ISSN: | 0009-4293 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Language: | English |
| Related URLs: | |
| edoc DOI: | |
| Last Modified: | 24 Apr 2017 14:15 |
| Deposited On: | 22 Mar 2012 14:06 |
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