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Palladium-catalyzed allylic substitution: reversible formation of allyl-bridged dinuclear palladium(I) complexes.

Markert, Christian and Neuburger, Markus and Kulicke, Klaus and Meuwly, Markus and Pfaltz, Andreas. (2007) Palladium-catalyzed allylic substitution: reversible formation of allyl-bridged dinuclear palladium(I) complexes. Angewandte Chemie International Edition, 46 (31). pp. 5892-5895.

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Official URL: http://edoc.unibas.ch/dok/A5250876

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Abstract

ESI-MS monitoring of the title reaction has led to the discovery that dinuclear allyl-bridged PdI complexes are formed reversibly in substantial amounts during catalysis (see scheme; Bz=benzoyl). The structure of one such complex was determined by X-ray analysis (see picture; P yellow, N blue, O red, Pd dark gray). Upon consumption of the starting materials a new dinuclear complex resulting from reductive C[BOND]Cl bond cleavage of CH2Cl2 was observed.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Physikalische Chemie (Meuwly)
UniBasel Contributors:Meuwly, Markus
Item Type:Article, refereed
Publisher:Wiley
ISSN:1433-7851
e-ISSN:1521-3773
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:10 Apr 2017 13:35
Deposited On:22 Mar 2012 13:33

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