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Large Work Function Shift of Gold Induced by a Novel Perfluorinated Azobenzene-Based Self-Assembled Monolayer

Crivillers, Núria and Osella, Silvio and Van Dyck, Colin and Lazzerini, Giovanni M. and Cornil, David and Liscio, Andrea and Di Stasio, Francesco and Mian, Shabbir and Fenwick, Oliver and Reinders, Federica and Neuburger, Markus and Treossi, Emanuele and Mayor, Marcel and Palermo, Vincenzo and Cacialli, Franco and Cornil, Jérôme and Samorì, Paolo. (2013) Large Work Function Shift of Gold Induced by a Novel Perfluorinated Azobenzene-Based Self-Assembled Monolayer. Advanced Materials , 25 (3). pp. 432-436.

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Official URL: http://edoc.unibas.ch/dok/A6083387

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Abstract

Tune it with light! Self-assembled monolayers on gold based on a chemisorbed novel azobenzene derivative with a perfluorinated terminal phenyl ring are prepared. The modified substrate shows a significant work function increase compared to the bare metal. The photo-conversion between trans and cis isomers chemisorbed on the surface shows great perspectives for being an accessible route to tune the gold properties by means of light.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Molecular Devices and Materials (Mayor)
UniBasel Contributors:Mayor, Marcel and Reinders, Federica and Neuburger, Markus
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:0935-9648
e-ISSN:1521-4095
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:05 Apr 2017 10:00
Deposited On:24 May 2013 09:05

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