Therrien, Bruno and Ward, Thomas R. and Pilkington, Melanie and Hoffmann, Christina and Gilardoni, Francois and Weber, Jacques. (1998) Synthesis and Reactivity of Tethered η1:η6-(Phosphinoarene)ruthenium Dichlorides. Organometallics, 17 (3). pp. 330-337.
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Official URL: http://edoc.unibas.ch/dok/A5254484
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Abstract
The coordination properties of ortho- and meta-substituted [(2-diphenylphosphanylethyl)phenyl]methanol 4a and 4b toward ruthenium(II) have been investigated. To ensure coordination of both the arene and the tethered phosphine, the labile ruthenium arene dimer [RuCl2(EtO2CC6H5)]2 (7) was synthesized and structurally characterized. Both the ortho and meta isomers [Ru(4a)Cl2] (9a) and [Ru(4b)Cl2] (9b) were characterized by X-ray crystallography. The lack of reactivity of the benzylic alcohol functionality in complexes 9a and 9b toward various P and C electrophiles is rationalized with extended Hückel calculations.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward) |
|---|---|
| UniBasel Contributors: | Ward, Thomas R. R. |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | American Chemical Society |
| ISSN: | 0276-7333 |
| e-ISSN: | 1520-6041 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 26 Apr 2017 14:03 |
| Deposited On: | 22 Mar 2012 14:07 |
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