Jimenez, Vicente G. and Mayorga-Burrezo, Paula and Blanco, Victor and Lloveras, Vega and Gomez-Garcia, Carlos J. and Solomek, Tomas and Cuerva, Juan M. and Veciana, Jaume and Campana, Araceli G.. (2020) Dibenzocycloheptatriene as end-group of Thiele and tetrabenzo-Chichibabin hydrocarbons. Chemical Communications , 56 (84). pp. 12813-12816.
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Abstract
Thiele (Th) and tetrabenzo-Chichibabin (TBC) derivatives with terminal dibenzocycloheptatriene (DBHept) units were prepared. A clear correlation between their electronic and molecular structures was stablished. Insights into their closed- or open-shell ground states were gained, where particular contribution of the heptagonal carbocycles as end-groups was proved. Remarkably, a thermally accessible triplet diradical configuration was confirmed for theDBHept-TBCcompound.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie 05 Faculty of Science > Departement Chemie > Chemie > Molecular Devices and Materials (Mayor) |
|---|---|
| UniBasel Contributors: | Solomek, Tomas |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| e-ISSN: | 1364-548X |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Language: | English |
| Identification Number: |
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| edoc DOI: | |
| Last Modified: | 03 Apr 2023 09:12 |
| Deposited On: | 03 Apr 2023 09:12 |
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