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Metallostars: High-nuclearity linearly developed nanostructures containing multiple cluster motifs

Constable, Edwin C. and Eich, O. and Fenske, D. and Housecroft, Catherine E. and Johnston, Lesley A.. (2000) Metallostars: High-nuclearity linearly developed nanostructures containing multiple cluster motifs. Chemistry - A European Journal, 6 (23). pp. 4364-4370.

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Official URL: https://edoc.unibas.ch/92780/

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Abstract

Metallostars are complexes in which a single branching site bears a number of metallated arms. Although they are related to metallodendrimers, they have the advantage of being capable of extending in an unlimited sense; in contrast to metallodendrimers, steric interactions decrease with increasing generation number. In this paper a series of polyalkyne stars with four and six arms, based upon a single tetrahedral carbon core and a benzene core, respectively, are reported and their reactions with [Co-2(CO)(8)] to give metallostars that contain multiple C2Co2(CO)(6) motifs are described.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:0947-6539
e-ISSN:1521-3765
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:19 Jan 2023 13:35
Deposited On:19 Jan 2023 13:35

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