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Concentration-Dependent Self-Assembly of an Unusually Large Hexameric Hydrogen-Bonded Molecular Cage

Merget, Severin and Catti, Lorenzo and Zev, Shani and Major, Dan T. and Trapp, Nils and Tiefenbacher, Konrad. (2021) Concentration-Dependent Self-Assembly of an Unusually Large Hexameric Hydrogen-Bonded Molecular Cage. Chemistry - A European Journal, 27 (13). pp. 4447-4453.

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Official URL: https://edoc.unibas.ch/86079/

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Abstract

A large, hexameric cage based on amide dimerization self-assembles from a designed macrocyclic building block in nonpolar solvents. The unusually large structure ( V ∼2800 Å 3 ) features openings commonly associated with covalently linked cages and forms host-guest complexes with fullerenes (C 60 and C 70 ). The formation of the hexameric structure was found to be strongly concentration dependent.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Synthesis of Functional Modules (Tiefenbacher)
UniBasel Contributors:Merget, Severin and Catti, Lorenzo and Tiefenbacher, Konrad
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:0947-6539
e-ISSN:1521-3765
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
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Last Modified:31 Jan 2022 15:23
Deposited On:24 Jan 2022 13:51

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