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Discrete Systems Related to Coordination Networks and Metal-Organic Frameworks

Constable, E. C. and Housecroft, C. E.. (2021) Discrete Systems Related to Coordination Networks and Metal-Organic Frameworks. In: Comprehensive Coordination Chemistry, 7, Pt. 15. Amsterdam, pp. 121-173.

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Abstract

Discrete coordination systems assembled from combinations of metal ions and organic ligands contrast with infinite networks and frameworks, but the fields are closely associated by their synthetic strategies. This review surveys design principles for the assembly of discrete rods (in contrast to infinite 1-dimensional coordination polymers), molecular helicates, metallogrids, metallostars, polygons (metallomacrocyles), and metallocages. Organic ligands with well-defined vectorial properties are key to directed assembly. Metal-based nodes may be mono- or multinuclear, and the principles used for directing assemblies through choice of appropriate metal center(s) are exemplifed.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth
Item Type:Book Section, refereed
Book Section Subtype:Further Contribution in a Book
Publisher:Elsevier
ISBN:978-0-08-102689-2
Note:Publication type according to Uni Basel Research Database: Book item
Language:English
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edoc DOI:
Last Modified:04 Aug 2021 15:44
Deposited On:04 Aug 2021 15:44

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