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Catechol[4]arene: The Missing Chiral Member of the Calix[4]arene Family

Nemat, Suren and Jedrzejewska, H. and Prescimone, Alessandro and Szumna, A. and Tiefenbacher, Konrad. (2020) Catechol[4]arene: The Missing Chiral Member of the Calix[4]arene Family. Organic Letters, 22 (14). pp. 5506-5510.

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Official URL: https://edoc.unibas.ch/81124/

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Abstract

A missing, inherently chiral member of the calix[4]arene family denoted "catechol[4]arene" was synthesized. Its properties were studied and compared to the ones of its close relatives resorcin[4]arene and pyrogallol[4]arene. This novel supramolecular host exhibits binding capabilities that are superior to its sister molecules in polar media. The enantiomerically pure forms of the macrocycle display modest recognition of chiral ammonium salts.
Faculties and Departments:05 Faculty of Science > Departement Chemie
05 Faculty of Science > Departement Chemie > Chemie > Synthesis of Functional Modules (Tiefenbacher)
UniBasel Contributors:Nemat, Suren and Prescimone, Alessandro and Tiefenbacher, Konrad
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:American Chemical Society
ISSN:1523-7060
e-ISSN:1523-7052
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
edoc DOI:
Last Modified:02 Mar 2021 15:41
Deposited On:16 Feb 2021 09:26

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