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Synthesis and Transport Studies of a Cofacial Porphyrin Cyclophane

Zwick, Patrick and Hsu, Chunwei and El Abbassi, Maria and Fuhr, Olaf and Fenske, Dieter and Dulic, Diana and van der Zant, Herre S. J. and Mayor, Marcel. (2020) Synthesis and Transport Studies of a Cofacial Porphyrin Cyclophane. Journal of Organic Chemistry, 85 (23). pp. 15072-15081.

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Official URL: https://edoc.unibas.ch/80536/

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Abstract

Porphyrin cyclophane 1 , consisting of two rigidly fixed but still movable cofacial porphyrins and exposing acetate-masked thiols in opposed directions of the macrocycle, is designed, synthesized, and characterized. The functional cyclophane 1 , as pioneer of mechanosensitive 3D materials, forms stable single-molecule junctions in a mechanically controlled break-junction setup. Its reliable integration in a single-molecule junction is a fundamental prerequisite to explore the potential of these structures as mechanically triggered functional units and devices.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Molecular Devices and Materials (Mayor)
UniBasel Contributors:Mayor, Marcel and Zwick, Patrick
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:American Chemical Society
ISSN:0022-3263
e-ISSN:1520-6904
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:11 Mar 2021 11:26
Deposited On:11 Mar 2021 11:26

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