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Concurrent Cross Metathesis and Enzymatic Oxidation: Enabling Off-Equilibrium Transformations

Koehler, Valentin and Ward, Thomas R.. (2014) Concurrent Cross Metathesis and Enzymatic Oxidation: Enabling Off-Equilibrium Transformations. ChemCatChem, 6 (8). pp. 2191-2193.

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Abstract

Criss‐cross catalysis: H. Zhao, J. F. Hartwig and co‐workers have combined homogeneous alkene metathesis and biocatalysis in a concurrent fashion. A ruthenium–N‐heterocyclic carbene (NHC) complex provides an equilibrating mixture of cross metathesis products. The selective simultaneous epoxidation by cytochrome P450 BM3 enables product yields well above the hypothetical two‐step process.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward)
UniBasel Contributors:Köhler, Valentin
Item Type:Article
Article Subtype:Further Journal Contribution
Publisher:Wiley
ISSN:1867-3880
e-ISSN:1867-3899
Note:Publication type according to Uni Basel Research Database: Journal item
Language:English
Identification Number:
Last Modified:23 Jun 2020 10:56
Deposited On:09 Jun 2020 09:00

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