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Redistribution of terpy ligands - approaches to new dynamic combinatorial libraries

Constable, Edwin C. and Housecroft, Catherine E. and Kulke, Torsten and Lazzarini, Chiarra and Schofield, Emma R. and Zimmermann, Yves. (2001) Redistribution of terpy ligands - approaches to new dynamic combinatorial libraries. Journal of the Chemical Society. Dalton Transactions (19). pp. 2864-2871.

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Official URL: https://edoc.unibas.ch/76368/

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Abstract

Mixing solutions of homoleptic cobalt(II) complexes [CoA(2)](2+) and [CoB2](2+) results in the establishment of a combinatorial library containing the heteroleptic complex [CoAB](2+) By using enantiomorphic ligands A and B the reactions may be followed by H-1 NMR spectroscopy. Exchange reactions with 6-substituted ligands are slower than those with 5- and 4-substituted species.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Article Subtype:Research Article
ISSN:1472-7773
e-ISSN:1364-5447
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:22 Apr 2020 14:06
Deposited On:22 Apr 2020 14:06

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