Nickel(II) chloride adducts of 4 '-phenyl-2,2 ': 6 ',2 ''-terpyridine

Constable, Edwin C. and Phillips, David and Raithby, Paul R.. (2002) Nickel(II) chloride adducts of 4 '-phenyl-2,2 ': 6 ',2 ''-terpyridine. Inorganic Chemistry Communications, 5 (7). pp. 519-521.

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The reaction of 4`-phenyl-2,2`:6`, 2``-terpyridine I with nickel(II) chloride gives a 1: 1 adduct which we have structurally characterised and shown to be comprised of two species of stoichiometry Ni(I)Cl-2; the first is a five-coordinate [Ni(I)Cl-2] complex and the other is a dinuclear species containing two six-coordinate nickel centres [(I)ClNi(mu-Cl)(2)Ni(I)Cl]. (C) 2002 Elsevier Science B.V. All rights reserved.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Article Subtype:Research Article
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:22 Apr 2020 13:22
Deposited On:22 Apr 2020 13:22

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