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How well do we understand self-assembly algorithms? From prototype grid to polymers

Constable, Edwin C. and Housecroft, Catherine E. and Kariuki, Benson M. and Kelly, Natalie and Smith, Christopher B.. (2002) How well do we understand self-assembly algorithms? From prototype grid to polymers. Comptes Rendus Chimie, 5 (5). pp. 425-430.

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Official URL: https://edoc.unibas.ch/76363/

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Abstract

Algorithms used for the assembly of metallosupramolecular constructs are simple and based upon well-established principles of coordination chemistry. The multinucleating ligand 3,6-bis(2-pyridyl)pyridazine forms a [2 x 2] grid with copper(l); the related ligand 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (dptz) is expected to behave in a similar manner with silver(l). However, instead of the expected grid, [Ag(dptz)(2)](+) Solution species are formed. In the solid state, dinuclear [Ag-2(dPtZ)(2)](2+) and polymeric [Ag(dptz-N,N`)(mu-dptz)(n)](n+) complexes have been structurally characterised.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:1631-0748
e-ISSN:1878-1543
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:22 Apr 2020 13:39
Deposited On:22 Apr 2020 13:39

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