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Interface-rich Aqueous Systems for Sustainable Chemical Synthesis

Kaldre, Dainis and Gallou, Fabrice and Sparr, Christof and Parmentier, Michael. (2019) Interface-rich Aqueous Systems for Sustainable Chemical Synthesis. Chimia, 73 (9). pp. 714-719.

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Official URL: https://edoc.unibas.ch/74205/

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Abstract

Mimicking an enzyme's exquisite activity and selectivity is a long-standing goal for sustainable chemical method development in aqueous media. The use of interface-rich aqueous systems, such as single-chain polymers, micelles and vesicle membranes recently emerged as strategy to emulate the compartmentalization of natural systems. In aqueous solution, aggregates such as micelles or microemulsion droplets are formed, providing reaction environments different from bulk solutions that frequently improve selectivity and accelerate reaction rates for a wide array of chemical transformations. We present here selected examples of interface-rich aqueous systems and discuss the advantages they offer for chemical synthesis. In particular metal-catalyzed cross-coupling reactions are highlighted and future challenges to perform reactions in interface-rich aqueous media are discussed.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Organische Chemie (Sparr)
UniBasel Contributors:Sparr, Christof and Kaldre, Dainis
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Schweizerische Chemische Gesellschaft
ISSN:0009-4293
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:01 Sep 2020 01:30
Deposited On:21 Jan 2020 12:11

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