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Near dissociation states for H2+-He on MRCI and FCI potential energy surfaces

Koner, Debasish and San Vicente Veliz, Juan Carlos and van der Avoird, Ad and Meuwly, Markus. (2019) Near dissociation states for H2+-He on MRCI and FCI potential energy surfaces. Physical Chemistry Chemical Physics, 21 (45). pp. 24976-24983.

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Abstract

New potential energy surfaces (PES) have been constructed for H2+-He using a reproducing kernel Hilbert space (RKHS) representation from an extensive number of ab initio energies computed at the multi reference and full configuration interaction levels of theory. For the MRCI PES the long-range interaction region of the PES is described by analytical functions and is connected smoothly to the short range interaction region, represented as a RKHS. All bound ro-vibrational states for the ground electronic state of H2+-He are calculated using two different methods to determine quantum bound states. Comparing transition frequencies for the near-dissociation states for ortho- and para-H2+-He allows assignment of the 15.2 GHz line to a J = 2 e/f parity doublet of ortho-H2+-He whereas the experimentally determined 21.8 GHz line is only consistent with a (J = 0) (J = 1) e/e transition in para-H2+-He.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Physikalische Chemie (Meuwly)
UniBasel Contributors:Meuwly, Markus and Koner, Debasish and San Vicente Veliz, Juan Carlos
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
ISSN:1463-9076
e-ISSN:1463-9084
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:03 Dec 2019 14:07
Deposited On:03 Dec 2019 14:07

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