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Trinodal Self-Penetrating Nets from Reactions of 1,4-Bis(alkoxy)-2,5-bis(3,2':6',3''-terpyridin-4'-yl)benzene Ligands with Cobalt(II) Thiocyanate

Manfroni, Giacomo and Prescimone, Alessandro and Batten, Stuart R. and Klein, Y. Maximilian. and Gawryluk, D. J. and Constable, Edwin C. and Housecroft, Catherine E.. (2019) Trinodal Self-Penetrating Nets from Reactions of 1,4-Bis(alkoxy)-2,5-bis(3,2':6',3''-terpyridin-4'-yl)benzene Ligands with Cobalt(II) Thiocyanate. Crystals, 9 (10). p. 529.

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Abstract

The tetratopic ligands 1,4-bis(2-ethylbutoxy)-2,5-bis(3,2':6',3''-terpyridin-4'-yl)benzene ( 1 ) and 1,4-bis(3-methylbutoxy)-2,5-bis(3,2':6',3''-terpyridin-4'-yl)benzene ( 2 ) have been prepared and characterized by 1 H and 13 C{ 1 H} NMR, IR, and absorption spectroscopies and mass spectrometry. Reactions of 1 and 2 with cobalt(II) thiocyanate under conditions of crystal growth at room temperature result in the formation of [{Co( 1 )(NCS) 2 }·MeOH·3CHCl 3 ] n and [{Co( 2 )(NCS) 2 }·0.8MeOH·1.8CHCl 3 ] n . Single-crystal X-ray diffraction reveals that each crystal lattice consists of a trinodal self-penetrating (6 2 .8 4 )(6 4 .8 2 )(6 5 .8) 2 net. The nodes are defined by two independent cobalt centres and the centroids of two crystallographically independent ligands which are topologically equivalent.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Housecroft, Catherine Elizabeth and Manfroni, Giacomo and Constable, Edwin Charles and Prescimone, Alessandro
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:MDPI
e-ISSN:2073-4352
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
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Last Modified:29 Oct 2019 14:09
Deposited On:29 Oct 2019 14:06

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