Rocco, Dalila and Housecroft, Catherine E. and Constable, Edwin C.. (2019) Synthesis of Terpyridines: Simple Reactions - What Could Possibly Go Wrong? Molecules, 24 (9). p. 1799.
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Abstract
The preparation of 24‐functionalized 12,22:26,32‐terpyridines (4′‐functionalized 3,2:6′,3′′‐terpyridines) by the reaction of three 4‐alkoxybenzaldehydes with 3‐acetylpyridine and ammonia was investigated; under identical reaction conditions, two (R = nC4H9, C2H5) gave the expected products whereas a third (R = nC3H7) gave only a cyclohexanol derivative derived from the condensation of three molecules of 3‐acetylpyridine with two of 4‐(n‐propoxy)benzaldehyde. A comprehensive survey of ′′unexpected′′ products from reactions of ArCOCH3 derivatives with aromatic aldehydes is presented. Three different types of alternative product are identified.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable) 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Housecroft) |
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| UniBasel Contributors: | Housecroft, Catherine Elizabeth and Constable, Edwin Charles and Rocco, Dalila |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | MDPI |
| e-ISSN: | 1420-3049 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Language: | English |
| Related URLs: | |
| Identification Number: |
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| edoc DOI: | |
| Last Modified: | 21 May 2019 08:12 |
| Deposited On: | 21 May 2019 08:12 |
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