Sensitized Triplet-Triplet Annihilation Upconversion in Water and its Application to Photochemical Transformations

Kerzig, Christoph and Wenger, Oliver S.. (2018) Sensitized Triplet-Triplet Annihilation Upconversion in Water and its Application to Photochemical Transformations. Chemical Science, 9 (32). pp. 6670-6678.

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Official URL: https://edoc.unibas.ch/67432/

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Sensitized triplet–triplet annihilation (TTA) is a promising mechanism for solar energy conversion, but so far its application has been practically completely limited to organic solvents and self-assembled or solid state systems. Combining water-soluble ruthenium complex–pyrene dyads with particularly long excited-state lifetimes as sensitizers and highly fluorescent commercial anthracenes as acceptors/annihilators, we were able to achieve green-to-violet upconversion with unprecedented quantum yields in pure water. Compared to the only known system exploiting sensitized TTA in homogeneous aqueous solution, we improve the overall photon upconversion efficiency by a full order of magnitude and present the very first example for a chemical transformation on a laboratory scale via upconversion in water. Specifically, we found that a thermodynamically challenging carbon–chlorine bond activation can be driven by green photons from an inexpensive continuous wave light source in the presence of dissolved oxygen. Our study is thus potentially relevant in the context of cleaning water from halogenated (toxic) contaminants and for sustainable photochemistry in the most environmentally friendly solvent.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Wenger)
UniBasel Contributors:Wenger, Oliver and Kerzig, Christoph
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
Note:Publication type according to Uni Basel Research Database: Journal article
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edoc DOI:
Last Modified:04 Apr 2019 11:06
Deposited On:04 Apr 2019 11:06

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