Rocaboy, Ronan and Dailler, David and Zellweger, Florian and Neuburger, Markus and Salomé, Christophe and Clot, Eric and Baudoin, Olivier. (2018) Domino Pd0-Catalyzed C(sp3)-H Arylation/Electrocyclic Reactions via Benzazetidine Intermediates. Angewandte Chemie International Edition, 57 (37). pp. 12131-12135.
Full text not available from this repository.
Official URL: https://edoc.unibas.ch/66277/
Downloads: Statistics Overview
Abstract
The Pd0-catalyzed C(sp3)-H arylation of 2-bromo-N-methylanilides leads to unstable benzazetidine intermediates that rearrange to benzoxazines through 4π electrocyclic ring-opening and 6π electrocyclization. The introduction of a bulky, non-activatable amide group on the nitrogen atom was key to favor the challenging reductive elimination step and disfavor undesired reaction pathways.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Synthetische Chemie (Baudoin) |
|---|---|
| UniBasel Contributors: | Baudoin, Olivier |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 1433-7851 |
| e-ISSN: | 1521-3773 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
|
| Last Modified: | 24 Oct 2018 14:33 |
| Deposited On: | 24 Oct 2018 14:33 |
Repository Staff Only: item control page