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Electronic absorption spectra of C60+ –L (L = He, Ne, Ar, Kr, H2, D2, N2) complexes

Holz, M. and Campbell, E. K. and Rice, C. A. and Maier, J. P.. (2017) Electronic absorption spectra of C60+ –L (L = He, Ne, Ar, Kr, H2, D2, N2) complexes. Journal of Molecular Spectroscopy, 332. pp. 22-25.

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Abstract

Electronic spectra in the near infrared of C60+ with He, Ne, Ar, Kr, H2, D2 and N2 attached have been recorded below 10 K in a cryogenic radio frequency ion trap. Additional absorption bands are observed compared to the spectrum of C60+ –He. In the case of C60+ –N2, the strongest one of these shifts to lower energies by 21.3 cm−1 compared to the origin band of C60+ –He at 10378.5 cm−1. The pattern in the spectrum is dependent on the attached ligand. The gas-phase observations on C60+ –Ne allow a rationalization of the relative intensities of the absorptions of C60+ in a neon matrix.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Physikalische Chemie (Maier)
UniBasel Contributors:Maier, John Paul and Holz, Mathias and Campbell, Ewen and Rice, Corey Allen
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:0022-2852
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:19 Jan 2018 14:34
Deposited On:05 Jan 2018 14:37

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