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Electronic Spectrum of Dihydrogenated Buckminsterfullerene in a 6 K Neon Matrix

Filipkowski, Karol and Rice, Corey Allen and Maier, John P.. (2017) Electronic Spectrum of Dihydrogenated Buckminsterfullerene in a 6 K Neon Matrix. ECS Journal of Solid State Science and Technology, 6 (6). M3028-M3030.

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Abstract

Vibrationally resolved electronic absorption spectrum of 1,2-dihydrogenated[60]fullerene has been recorded in a 6 K neon matrix after mass-selected deposition of m/z = 722 cations produced from reaction of protonated methane and C60 in an ion source. One system has the origin band at 688.5 ± 0.1 nm and another commencing at 404.8 ± 0.1 nm. Theoretical computations were used to calculate the relative energies of three isomers of dihydrogenated[60]fullerene and time-dependent density functional theory predicted the vertical excitations to 50 electronic states.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Physikalische Chemie (Maier)
UniBasel Contributors:Maier, John Paul and Filipkowski, Karol and Rice, Corey Allen
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Electrochemical Society
ISSN:2162-8769
e-ISSN:2162-8777
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:05 Jan 2018 13:03
Deposited On:05 Jan 2018 13:02

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