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Tetratopic bis(4,2′:6′,4′′-terpyridine) and bis(3,2′:6′,3′′-terpyridine) Ligands as 4-Connecting Nodes in 2D-Coordination Networks and 3D-Frameworks

Constable, Edwin C. and Housecroft, Catherine E.. (2018) Tetratopic bis(4,2′:6′,4′′-terpyridine) and bis(3,2′:6′,3′′-terpyridine) Ligands as 4-Connecting Nodes in 2D-Coordination Networks and 3D-Frameworks. Journal of Inorganic and Organometallic Polymers and Materials, 28. pp. 414-427.

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Official URL: http://edoc.unibas.ch/57936/

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Abstract

Ditopic, 4,2':6',4''-terpyridine (4,2':6',4''-tpy) and 3,2':6',3''-terpyridine (3,2':6',3''-tpy) present a divergent N,N' -donor set (the central N atom typically being non-coordinated) and are ideal building blocks for the assembly of coordination polymers and networks. The step from ditopic to tetratopic ligands which contain two interconnected 4,2':6',4''-tpy or 3,2':6',3''-tpy metal-binding domains renders the ligand capable of acting as a 4-connecting node and is a successful route to increasing the dimensionality of the assembly. In this short overview, we illustrate the recent development of the use of bis(4,2':6',4''-tpy) and bis(3,2':6',3''-tpy) ligands and compare strategies using either ditopic or tetratopic ligands.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Housecroft, Catherine Elizabeth and Constable, Edwin Charles
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Springer
ISSN:1574-1443
e-ISSN:1574-1451
Note:Publication type according to Uni Basel Research Database: Journal article -- The final publication is available at Springer see DOI link
Language:English
Identification Number:
Last Modified:14 Mar 2018 10:24
Deposited On:27 Dec 2017 13:32

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