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Absolute ion hydration enthalpies and the role of volume within hydration thermodynamics

Housecroft, Catherine E. and Jenkins, H. Donald Brooke. (2017) Absolute ion hydration enthalpies and the role of volume within hydration thermodynamics. RSC Advances, 7 (45). pp. 27881-27894.

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Abstract

This paper reports that various thermodynamic properties in aqueous media for certain individual ions and for compounds are linear functions of the inverse cube root of the solid respective ionic and compound solid state volumes, V m –1/3 . This is similar to the situation which has been fully exploited in solid state thermodynamics and out of which Volume–Based Thermodynamics, VBT evolved. A short resume of these various VBT applications is provided for the general reader and an improved lattice potential energy equation emerges using the state of the art data presented in this paper.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Housecroft, Catherine Elizabeth
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
e-ISSN:2046-2069
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:07 Jun 2017 08:32
Deposited On:07 Jun 2017 08:32

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