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New silver complexes with ligands based on 4-substituted-3,6-dipyridin-2-ylpyridazines

Reymann, Sébastien. New silver complexes with ligands based on 4-substituted-3,6-dipyridin-2-ylpyridazines. 2007, Doctoral Thesis, University of Basel, Faculty of Science.

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Official URL: http://edoc.unibas.ch/diss/DissB_7857

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Abstract

Chapter I gives a brief introduction to supramolecular chemistry, silver chemistry,
pyridazine chemistry.
Chapter II discusses the general procedure used for this work. It introduces the
Sonogashira reaction used to prepare the ethynyl precursors, and the inverse
electron demand Diels Alder reaction used to synthesise all the ligands presented in
this work.
Chapter III describes the synthesis and the characterisation of phenyl substituted
pyridazines and their silver complexes. This chapter presents the crystal structure of
ligand 8.
Chapter IV discusses the synthesis and characterisation of the halogenated
pyridazine and their silver complexes. It also discusses the crystal structure of ligand
15 and complexes 15sc, 18sc and 20sc.
Chapter V describes the synthesis of diverse pyridazines. These ligands have
methoxy, cyano, tert-butyl phenyl substituents. It also shows the crystal structure of
ligand 34 and complexes 30sc, 39sc, 42sc, 43sc and 49sc.
Chapter VI discusses the synthesis and characterisation of pyridazine substituted
with alkyl chains. The crystal structure of complex 53sc is presented.
Chapter VII gives the conclusion to this work and a general overview of the ligands
and complexes synthesised in this thesis.
Advisors:Constable, Edwin C.
Committee Members:Pfaltz, Andreas
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
UniBasel Contributors:Pfaltz, Andreas
Item Type:Thesis
Thesis Subtype:Doctoral Thesis
Thesis no:7857
Thesis status:Complete
Bibsysno:Link to catalogue
Number of Pages:265
Language:English
Identification Number:
Last Modified:22 Jan 2018 15:50
Deposited On:13 Feb 2009 15:55

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