Braeuer, Thomas M. and Zhang, Qi and Tiefenbacher, Konrad. (2016) Iminium Catalysis inside a Self-Assembled Supramolecular Capsule: Modulation of Enantiomeric Excess. Angewandte Chemie International Edition, 55 (27). pp. 7698-7701.
Full text not available from this repository.
Official URL: http://edoc.unibas.ch/52652/
Downloads: Statistics Overview
Abstract
The noncovalent combination of a supramolecular host with iminium organocatalysis is described. Due to cation-pi interactions the reactive iminium species is held inside the host and reacts in this confined environment. The products formed differ up to 92% ee from the control experiments without added host. A model rationalizing the observed difference is presented.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Organische Chemie (Sparr) 05 Faculty of Science > Departement Chemie > Chemie > Synthesis of Functional Modules (Tiefenbacher) |
|---|---|
| UniBasel Contributors: | Tiefenbacher, Konrad Karl |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 1433-7851 |
| e-ISSN: | 1521-3773 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
|
| Last Modified: | 14 Jun 2017 09:28 |
| Deposited On: | 14 Jun 2017 09:28 |
Repository Staff Only: item control page