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PEG Brushes on Porous, PDMS-Coated Surfaces and Their Interaction with Carbon Dioxide

Gunkel-Grabole, Gesine and Car, Anja and Naik, Vikrant V. and Marot, Laurent and Ferk, Gregor and Palivan, Cornelia and Meier, Wolfgang. (2016) PEG Brushes on Porous, PDMS-Coated Surfaces and Their Interaction with Carbon Dioxide. Macromolecular Chemistry and Physics, 217 (8). pp. 966-973.

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Official URL: http://edoc.unibas.ch/44447/

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Abstract

A porous polymeric substrate covered with a thin polydimethylsiloxane (PDMS) coating is used for the surface-initiated polymerization of polyethylene glycol (PEG)-based polymer brushes. Successful synthesis of the brushes is evidenced by several methods and their impact on the characteristics of the polymeric multilayer substrate is studied. Investigation into the behavior of PEG-based brushes using atomic force microscopy and multiple transmission-reflection infrared (MTR-FTIR) spectroscopy reveals conformational changes of the brush chains upon exposure to carbon dioxide. The results presented here highlight an elegant way to covalently modify porous, PDMS-coated substrates with polymer brushes to alter their characteristics.
Faculties and Departments:05 Faculty of Science > Departement Chemie
05 Faculty of Science > Departement Chemie > Chemie > Makromolekulare Chemie (Meier)
UniBasel Contributors:Meier, Wolfgang P.
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:1022-1352
e-ISSN:1521-3935
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:17 Oct 2016 08:16
Deposited On:17 Oct 2016 08:16

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