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Constructing chiral MOFs by functionalizing 4,2′:6′,4″-terpyridine with long-chain alkoxy domains: rare examples of neb nets

Klein, Y. M. and Prescimone, A. and Pitak, M. B. and Constable, E. C. and Housecroft, C. E.. (2016) Constructing chiral MOFs by functionalizing 4,2′:6′,4″-terpyridine with long-chain alkoxy domains: rare examples of neb nets. CrystEngComm, 18. pp. 4704-4707.

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Abstract

Reactions of 4′-(4- n alkyloxyphenyl)-4,2′:6′,4″-terpyridines (alkyl = hexyl or nonyl) with CoIJNCS) 2 lead to three structurally characterized chiral 3D assemblies which adopt rare neb topologies. For the n hexyl-functionalized ligands, both enantiomorphic lattices of the neb nets (crystallizing in the tetragonal space groups P4 1 2 1 2 and P4 3 2 1 2, respectively) are presented
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Housecroft, Catherine Elizabeth and Constable, Edwin Charles and Klein, Maximilian and Prescimone, Alessandro
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Royal Society of Chemistry
e-ISSN:1466-8033
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:10 Aug 2016 11:54
Deposited On:10 Aug 2016 11:54

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