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A double-stranded 1D-coordination polymer assembled using the tetravergent ligand 1,1′-bis(4,2′:6′,4″-terpyridin-4′-yl)ferrocene

Klein, Y. M. and Prescimone, A. and Constable, E. C. and Housecroft, C. E.. (2016) A double-stranded 1D-coordination polymer assembled using the tetravergent ligand 1,1′-bis(4,2′:6′,4″-terpyridin-4′-yl)ferrocene. Inorganic chemistry communications, 70. pp. 118-120.

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Abstract

1,1′-Bis(4,2′:6′,4″-terpyridin-4′-yl)ferrocene (1) reacts with ZnCl2 to yield a double-stranded 1D-coordination polymer [{Zn2(1)Cl4}∙3CHCl3]n. The 1,1′-functionalized ferrocene core adopts a cisoid-conformation, giving rise to a folded conformation for 1 and a double-stranded 1D-polymer chain. This contrasts with previously reported multi-stranded chains supported by 4,2′:6′,4″-terpyridine ligands in which the multiple-nature of the chain arises from multinuclear metal nodes.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Housecroft, Catherine Elizabeth and Constable, Edwin Charles and Klein, Maximilian and Prescimone, Alessandro
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:1387-7003
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:30 Jun 2016 11:04
Deposited On:21 Jun 2016 14:15

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