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Modular ligands for dirhodium complexes facilitate catalyst customization

Bachmann, Daniel and Schmidt, Pascal and Geigle, Stefanie and Chougnet, Antoinette and Woggon, Wolf-Dietrich and Gillingham, Dennis. (2015) Modular ligands for dirhodium complexes facilitate catalyst customization. Advanced Synthesis and Catalysis, 357 (9). pp. 2033-2038.

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Official URL: http://edoc.unibas.ch/41902/

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Abstract

Although stereoselectivity is often the focus of ligand optimizations in catalysis, ligand modularity can be used to control many other properties of catalysts. For example, solubility, amenability to purification, and steric shielding of sensitive catalytic intermediates are all important, but seldom appreciated, functions of ligands. We describe a brief and modular approach to various homo- and heteroleptic lantern-type rhodium(II) complexes and perform benchmarking studies with the new catalysts in common rhodium(II)-catalyzed reactions. We demonstrate the power of ligand modularity by creating catalysts customized for aqueous catalysis or for applications in chemical biology.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Organische Chemie (Gillingham)
UniBasel Contributors:Gillingham, Dennis and Schmidt, Pascal
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:1615-4150
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:17 Mar 2017 12:48
Deposited On:21 Apr 2016 14:36

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