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Gas Phase Detection of Benzocyclopropenyl

Maity, Surajit and Steglich, Mathias and Maier, John P.. (2015) Gas Phase Detection of Benzocyclopropenyl. The journal of physical chemistry. A, 119 (44). pp. 10849-10853.

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Official URL: http://edoc.unibas.ch/39821/

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Abstract

The gas phase detection of benzocyclopropenyl is reported. In this aromatic resonance stabilized radical, a large angular strain is present due to a three-membered ring annelated to a benzene. The resonant two-color two-photon ionization technique is used to record the D1(2A2) ← D0(2B1) electronic transition of this radical after the in situ synthesis in a discharge source. The spectrum features absorptions up to 3300 cm–1 above the origin band at 19 305 cm–1. Benzocyclopropenyl is possibly the major product of the bimolecular reaction of benzene and an atomic carbon at low temperatures.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Physikalische Chemie (Maier)
UniBasel Contributors:Maier, John Paul and Maity, Surajit and Steglich, Mathias
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:American Chemical Society
ISSN:1089-5639
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:30 Jun 2016 11:00
Deposited On:02 May 2016 10:00

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