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Chiral induction in a ribose-decorated metallostar through intrinsic and interionic diastereomeric interactions

Constable, Edwin C. and Frantz, R. and Housecroft, Catherine E. and Lacour, J. and Mahmood, A.. (2004) Chiral induction in a ribose-decorated metallostar through intrinsic and interionic diastereomeric interactions. Inorganic Chemistry, 43 (16). pp. 4817-4819.

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Official URL: http://edoc.unibas.ch/39199/

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Abstract

A ribose-functionalized bpy ligand has been prepared and shown to give modest diastereomeric excesses of Lambda-[FeL3](2+) complexes; interconversion of Delta and Lambda cations is relatively fast, and in CHCl3, the favored complexes with Delta- or Lambda-TRISPHAT counterions are homochiral, (Delta(+)Delta(-)) or (Delta(+)Lambda(-)). In the case of the Delta-TRISPHAT salt, a single diastereomer is observed (de greater than or equal to 96Publisher = AMER CHEMICAL SOC
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:American Chemical Society
ISSN:0020-1669
e-ISSN:1520-510X
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 08:52
Deposited On:03 Feb 2016 09:30

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