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Preparation and structural characterization of a dicopper prehelicate

Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, M. and Schaffner, S. and Shardlow, E. J.. (2005) Preparation and structural characterization of a dicopper prehelicate. Inorganic Chemistry Communications, 8 (8). pp. 743-745.

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Official URL: http://edoc.unibas.ch/39187/

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Abstract

In the reaction of 4`-(4-ethynylphenyl)-2,2`:6`,2``-terpyridine (3) with trans- [PtI2(PEt3)(2)] and CuI, ligand 3 scavenges Cu(I) and forms [Cu-2(PPh3)(2)(mu-I)(mu-3)]I, structural characterization of which shows that ligand 3 adopts a helical twist that parallels that found in related double helicates.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:1387-7003
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 08:35
Deposited On:03 Feb 2016 08:26

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