edoc

Bis[mu(2)-bis(diphenylphosphino)methane]-1 : 2 kappa P-2 : P `;2 : 3 kappa P-2 : P `-dichlorido-1 kappa Cl,3 kappa Cl-triangulo-trigold(I) hexafluorophosphate

Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia and Shardlow, Ellen J.. (2007) Bis[mu(2)-bis(diphenylphosphino)methane]-1 : 2 kappa P-2 : P `;2 : 3 kappa P-2 : P `-dichlorido-1 kappa Cl,3 kappa Cl-triangulo-trigold(I) hexafluorophosphate. Acta Crystallographica Section E: Structure Reports Online, 63 (6). M1698-U1084.

[img]
Preview
PDF - Published Version
Available under License CC BY (Attribution).

758Kb

Official URL: http://edoc.unibas.ch/39165/

Downloads: Statistics Overview

Abstract

In the title compound, [Au3Cl2(C25H22P2)(2)](PF6), the cation possesses a triangular Au-3 core [Au-Au distances 3.1525 (4), 3.2770 (4) and 3.1922 (4) angstrom], two sides of which are bridged by dppm ligands [dppm = bis(diphenylphosphino) methane]. One phenyl group is disordered over two positions in a 0.65:0.35 ratio. The structure of the cation is compared with those in three other salts reported previously.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
UniBasel Contributors:Constable, Edwin Charles
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:International Union of Crystallography
ISSN:1600-5368
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:12 Apr 2017 07:14
Deposited On:26 Jan 2016 07:53

Repository Staff Only: item control page