edoc

Tuning peripheral π-stacking motifs in {Cr(tpy)2}3+ domains (tpy = 2,2':6',2''-terpyridine)

Schönle, J. and Constable, E. C. and Housecroft, C. E. and Neuburger, M.. (2015) Tuning peripheral π-stacking motifs in {Cr(tpy)2}3+ domains (tpy = 2,2':6',2''-terpyridine). Inorganic Chemistry Communications, 53. pp. 80-83.

[img] PDF - Accepted Version
Available under License CC BY-NC-ND (Attribution-NonCommercial-NoDerivatives).

888Kb

Official URL: http://edoc.unibas.ch/dok/A6348158

Downloads: Statistics Overview

Abstract

The homoleptic complexes [Cr(1)2][PF6]3 and [Co(1)2][PF6]3 (1 = 4'-(naphth-2-yl)-2,2':6',2''-terpyridine) have been prepared and structurally characterized. The packing interactions in both complexes are identical, consisting of a combination of naphthyl...naphthyl π-stacking interactions and double naphthyl...pyridine embraces generating chains of cations with alternating long and short M...M contacts.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Housecroft, Catherine Elizabeth and Constable, Edwin Charles and Schönle, Jonas and Neuburger, Markus
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:1387-7003
Note:Publication type according to Uni Basel Research Database: Journal article
Language:English
Identification Number:
Last Modified:11 Oct 2017 12:36
Deposited On:10 Apr 2015 09:12

Repository Staff Only: item control page