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Biocatalytic ATRP: Controlled radical polymerizations mediated by enzymes

Kasper, Renggli and Mariana, Spulber and Jonas, Pollard and Martin, Rother and Nico, Bruns. (2013) Biocatalytic ATRP: Controlled radical polymerizations mediated by enzymes. In: Green polymer chemistry. Biocatalysis and biomaterials. Washington, DC, pp. 163-171.

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Official URL: http://edoc.unibas.ch/dok/A6212051

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Abstract

The advent of controlled radical polymerizations has made polymer science a key discipline for the preparation of nano-, biomedical-, and high tech-materials. Atom transfer radical polymerization (ATRP) is one of the most widely applied controlled radical polymerization. However, an ongoing quest is to develop ATRP reaction conditions that allow reducing the amount of catalyst needed, or to replace the currently used transition metal complex catalysts with less toxic ones. Using enzymes as catalysts is a classic strategy in the green chemistry approach, and many enzymatic polymerizations are known. However, controlled radical polymerizations that are catalyzed by enzymes or proteins were not known until our discovery that the metalloproteins horseradish peroxidase and hemoglobin can polymerize vinyl-monomers under conditions of activators regenerated by electron transfer (ARGET) ATRP. In this book chapter, we review the emerging field of biocatalytic ATRP.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie
05 Faculty of Science > Departement Chemie > Chemie > Makromolekulare Chemie (Meier)
UniBasel Contributors:Bruns, Nico and Renggli, Kasper and Spulber, Mariana and Pollard, Jonas and Rother, Martin
Item Type:Book Section, refereed
Book Section Subtype:Further Contribution in a Book
Bibsysno:Link to catalogue
Publisher:American Chemical Society
Note:Publication type according to Uni Basel Research Database: Book item
Identification Number:
Last Modified:04 Sep 2015 14:32
Deposited On:06 Mar 2015 07:44

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