Genz, Maika and Köhler, Valentin and Krauss, Michael and Singer, David and Hoffmann, Ralf and Ward, Thomas R. and Sträter, Norbert. (2014) An Artificial Imine Reductase Based on the RNAse S Scaffold. ChemCatChem, 6 (3). pp. 736-740.
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Official URL: http://edoc.unibas.ch/dok/A6338944
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Abstract
Dative anchoring of a piano-stool complex within ribonuclease S resulted in an artificial imine reductase. The catalytic performance was modulated upon variation of the coordinating amino acid residues in the S-peptide. Binding of Cp*Ir (Cp*=C5Me5) to the native active site resulted in good conversions and moderate enantiomeric excess values for the synthesis of salsolidine.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward) |
|---|---|
| UniBasel Contributors: | Köhler, Valentin and Ward, Thomas R. |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 1867-3880 |
| e-ISSN: | 1867-3899 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: | |
| Last Modified: | 03 May 2017 06:40 |
| Deposited On: | 06 Mar 2015 07:44 |
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