An Artificial Imine Reductase Based on the RNAse S Scaffold

Genz, Maika and Köhler, Valentin and Krauss, Michael and Singer, David and Hoffmann, Ralf and Ward, Thomas R. and Sträter, Norbert. (2014) An Artificial Imine Reductase Based on the RNAse S Scaffold. ChemCatChem, 6 (3). pp. 736-740.

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Official URL: http://edoc.unibas.ch/dok/A6338944

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Dative anchoring of a piano-stool complex within ribonuclease S resulted in an artificial imine reductase. The catalytic performance was modulated upon variation of the coordinating amino acid residues in the S-peptide. Binding of Cp*Ir (Cp*=C5Me5) to the native active site resulted in good conversions and moderate enantiomeric excess values for the synthesis of salsolidine.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward)
UniBasel Contributors:Köhler, Valentin and Ward, Thomas R.
Item Type:Article, refereed
Article Subtype:Research Article
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:03 May 2017 06:40
Deposited On:06 Mar 2015 07:44

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