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Electronic Absorption Spectrum of Triacetylene Cation for Astronomical Considerations

Chakrabarty, S. and Rice, C. A. and Mazzotti, F. J. and Dietsche, R. and Maier, J. P.. (2013) Electronic Absorption Spectrum of Triacetylene Cation for Astronomical Considerations. The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, and general theory, Vol. 117, H. 39. pp. 9574-9577.

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Official URL: http://edoc.unibas.ch/dok/A6194512

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Abstract

The A2Πg ← X2Πu electronic transition (4800–6000 Å) of triacetylene cation was measured in an ion trap, where the vibrational and rotational degrees of freedom were equilibrated to 25 K. The rotational profile of the origin band is predicted by a collisional-radiative rate model under conditions expected in diffuse interstellar clouds. Variation in the density of the surrounding gas, rotational temperature, and velocity dispersion are taken into account.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Physikalische Chemie (Maier)
UniBasel Contributors:Maier, John Paul and Chakrabarty, Satrajit and Mazzotti, Fabio Jerome and Dietsche, Rainer Matthias and Rice, Corey Allen
Item Type:Article, refereed
Article Subtype:Research Article
Bibsysno:Link to catalogue
Publisher:American Chemical Society
ISSN:1089-5639
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:06 Dec 2013 09:35
Deposited On:06 Dec 2013 09:35

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