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Iron(II) and ruthenium(II) complexes of 4′-amino-functionalised 2,2′:6′,2″-terpyridines

Tao, Yaqiu and Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus. (2012) Iron(II) and ruthenium(II) complexes of 4′-amino-functionalised 2,2′:6′,2″-terpyridines. Polyhedron, 33 (1). pp. 267-272.

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Official URL: http://edoc.unibas.ch/dok/A6056191

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Abstract

Six iron(II) and ruthenium(II) complexes of 4`-amino-functionalised 2,2`:6`,2 ``-terpyridines (4`-Rtpy) in which R = PhNH (1), 4-MeOC6H4NH (2) and 3,5-Me2C6H3NH (3) have been prepared and fully characterised. We have determined the single crystal structures of [Fe(1)(2)][PF6](2)center dot MeCN. [Fe(2)(2)][PF6](2)center dot MeCN and [Ru(2)(2)][PF6](2) and illustrate how the pendant substituents affect the pi-stacking interactions between tpy domains of adjacent cations in the solid state.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:0277-5387
e-ISSN:1873-3719
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:10 Apr 2017 14:14
Deposited On:01 Feb 2013 08:41

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