Gold(I) phosphine-decorated 2,2′:6′,2″-terpyridine ligands

Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia and Shardlow, Ellen J.. (2008) Gold(I) phosphine-decorated 2,2′:6′,2″-terpyridine ligands. Polyhedron, 27 (1). pp. 65-70.

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Official URL: http://edoc.unibas.ch/dok/A6056008

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The synthesis and characterization of the ligands R3PAu(1-H) (R =Bu-n, Ph) and (1-H)Au(mu-dppe)Au(1-H) (1 = HC CCH(2)Otpy, tpy = 2,2 `:6 `,2 ``-terpyridme) are reported. The single crystal structures of (Bu3PAu)-Bu-n(1-H) and (1-H)Au(mu-dppe)Au(1-H) have been determined, and weak hydrogen bonding rather than aurophilic interactions operate between the molecules in the solid state.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus
Item Type:Article, refereed
Article Subtype:Research Article
Note:Publication type according to Uni Basel Research Database: Journal article
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Last Modified:12 Apr 2017 07:03
Deposited On:01 Feb 2013 08:40

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