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A new polymorph of 4'-tolyl-2,2':6',2''-terpyridine (ttpy) and the single crystal structures of [Fe(ttpy)2][PF6]2 and [Ru(ttpy)2][PF6]2

Beves, Jonathon E. and Chwalisz, Paulina and Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia and Zampese, Jennifer A.. (2008) A new polymorph of 4'-tolyl-2,2':6',2''-terpyridine (ttpy) and the single crystal structures of [Fe(ttpy)2][PF6]2 and [Ru(ttpy)2][PF6]2. Inorganic Chemistry Communications, 11 (9). pp. 1009-1011.

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Official URL: http://edoc.unibas.ch/dok/A6055993

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Abstract

Single crystals of a new polymorph of 4`-tolyl-2,2`:6`,2 ``-terpyridine (ttpy) have been grown by evaporation of a hexane-ethyl acetate solution of the ligand; the packing features weak pi-stacking and N-Pyridine...HC interactions between stacks of ttpy molecules. Improved syntheses of [M(ttpy)(2)][PFr](2) (M = Fe, Ru), and the single crystal structures of [Fe(ttpy)(2)][PF6](2)center dot 2.2MeCN and [Ru(ttpy)21[PF6](2)center dot 1.75MeCN center dot 0.2H(2)O are reported.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Constable)
05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Housecroft)
UniBasel Contributors:Constable, Edwin Charles and Housecroft, Catherine Elizabeth and Neuburger, Markus
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:1387-7003
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:12 Apr 2017 06:33
Deposited On:01 Feb 2013 08:40

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